Photoswitchable Nonlinear-Optical Crystal Based on a Dysprosium–Iron Nitrosyl Metal Assembly

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  • Masaya Komine
    Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
  • Kenta Imoto
    Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
  • Asuka Namai
    Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
  • Marie Yoshikiyo
    Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
  • Shin-ichi Ohkoshi
    Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

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説明

Nitrosyl metal complexes (M-NO), in which nitrosyl ligands are coordinated to transition-metal ions, have been studied from the viewpoints of physiological activity, catalytic activity, and photosensitivity. The structural flexibility and electric polarization of the nitrosyl ligand are attractive characteristics. Herein we show a photoswitchable nonlinear-optical (NLO) crystal based on a dysprosium-iron nitrosyl assembly. This crystal is composed of a one-dimensional chain structure in the polar

収録刊行物

  • Inorganic Chemistry

    Inorganic Chemistry 60 (4), 2097-2104, 2021-01-26

    American Chemical Society (ACS)

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