Incorporating Thermally Activated Delayed Fluorescence into Mechanochromic Luminescent Emitters: High‐Performance Solution‐Processed Yellow Organic Light Emitting Diodes

  • Xuan Zeng
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
  • Tao Zhou
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
  • Jiangle Liu
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
  • Kailong Wu
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
  • Shuqi Li
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
  • Xiao Xiao
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
  • Yu Zhang
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
  • Shaolong Gong
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
  • Guohua Xie
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
  • Chuluo Yang
    Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China

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<jats:title>Abstract</jats:title><jats:p>Multifunctional materials with stimuli‐responsive features are demonstrated to be promising smart materials. In this work, three multifunctional materials, namely <jats:bold>5TzPmPXZ</jats:bold>, <jats:bold>7TzPmPXZ,</jats:bold> and <jats:bold>5,7TzPmPXZ</jats:bold>, are constructed by integrating phenoxazine with electron‐acceptor core [1,2,4]triazolo[1,5‐<jats:italic>a</jats:italic>]pyrimidine (TzPm). Intriguingly, these materials exhibit not only thermally activated delayed fluorescence but also multicolor luminescence switching which is caused by the phase transitions between microcrystalline and amorphous states upon external stimuli. Moreover, the solution‐processed organic light emitting diodes (OLEDs) fabricated with these materials furnish a high external quantum efficiency up to 14.3% and the Commission Internationale de l'Eclairage coordinates of (0.43, 0.53), which represents the state‐of‐the‐art performance for solution‐processed yellow OLEDs.</jats:p>

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