Incorporating Thermally Activated Delayed Fluorescence into Mechanochromic Luminescent Emitters: High‐Performance Solution‐Processed Yellow Organic Light Emitting Diodes
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- Xuan Zeng
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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- Tao Zhou
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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- Jiangle Liu
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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- Kailong Wu
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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- Shuqi Li
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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- Xiao Xiao
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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- Yu Zhang
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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- Shaolong Gong
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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- Guohua Xie
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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- Chuluo Yang
- Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan 430072 P. R. China
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説明
<jats:title>Abstract</jats:title><jats:p>Multifunctional materials with stimuli‐responsive features are demonstrated to be promising smart materials. In this work, three multifunctional materials, namely <jats:bold>5TzPmPXZ</jats:bold>, <jats:bold>7TzPmPXZ,</jats:bold> and <jats:bold>5,7TzPmPXZ</jats:bold>, are constructed by integrating phenoxazine with electron‐acceptor core [1,2,4]triazolo[1,5‐<jats:italic>a</jats:italic>]pyrimidine (TzPm). Intriguingly, these materials exhibit not only thermally activated delayed fluorescence but also multicolor luminescence switching which is caused by the phase transitions between microcrystalline and amorphous states upon external stimuli. Moreover, the solution‐processed organic light emitting diodes (OLEDs) fabricated with these materials furnish a high external quantum efficiency up to 14.3% and the Commission Internationale de l'Eclairage coordinates of (0.43, 0.53), which represents the state‐of‐the‐art performance for solution‐processed yellow OLEDs.</jats:p>
収録刊行物
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- Advanced Optical Materials
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Advanced Optical Materials 6 (24), 1801071-, 2018-10-23
Wiley