A New Protocol for Catalytic Reduction of Alkyl Chlorides Using an Iridium/Bis(benzimidazol-2′-yl)pyridine Catalyst and Triethylsilane
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- Takahide Fukuyama
- Department of Chemistry, Graduate School of Science, OsakaPrefecture University
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- Ilhyong Ryu
- Organization for Research Promotion, Osaka Prefecture University
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- Yuki Hamada
- Department of Chemistry, Graduate School of Science, OsakaPrefecture University
抄録
<jats:title>Abstract</jats:title><jats:p>The reduction of alkyl chlorides using triethylsilane is investigated. Primary, secondary, tertiary, and benzylic C–Cl bonds are effectively converted into C–H bonds using an [IrCl(cod)]2/2,6-bis(benzimidazol-2′-yl)pyridine catalyst system. This catalyst system is quite simple since the tridentate N-ligand can be easily prepared in one step from commercially available reagents.</jats:p>
収録刊行物
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- Synthesis
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Synthesis 53 (18), 3404-3408, 2021-06-11
Georg Thieme Verlag KG
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詳細情報 詳細情報について
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- CRID
- 1360294643759416704
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- ISSN
- 1437210X
- 00397881
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- データソース種別
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- Crossref
- KAKEN