Inverse Kinetic and Equilibrium Isotope Effects on Self‐Assembly and Supramolecular Chirality of Porphyrin J‐Aggregates

DOI Web Site Web Site 被引用文献1件
  • Roberto Zagami
    CNR-ISMN Istituto per lo Studio dei Materiali Nanostrutturati c/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina V.le F. Stagno D'Alcontres 31 98166 Messina Italy), Fax
  • Andrea Romeo
    CNR-ISMN Istituto per lo Studio dei Materiali Nanostrutturati c/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina V.le F. Stagno D'Alcontres 31 98166 Messina Italy), Fax
  • Maria A. Castriciano
    CNR-ISMN Istituto per lo Studio dei Materiali Nanostrutturati c/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina V.le F. Stagno D'Alcontres 31 98166 Messina Italy), Fax
  • Luigi Monsù Scolaro
    CNR-ISMN Istituto per lo Studio dei Materiali Nanostrutturati c/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina V.le F. Stagno D'Alcontres 31 98166 Messina Italy), Fax

書誌事項

公開日
2016-11-29
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/chem.201604675
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>When mixtures of D<jats:sub>2</jats:sub>O/DCl are used to foster the self‐assembly formation of TPPS<jats:sub>4</jats:sub> porphyrin J‐aggregates in aqueous solutions, an inverse kinetic isotope effect of 0.4 and an inverse equilibrium isotope effect of 0.6 are clearly detected. Most importantly, the addition of at least 10 % D<jats:sub>2</jats:sub>O causes an inversion in the handedness of the final chiral J‐aggregates, thus evidencing an important role of deuterium in driving the enantiomeric excess in the scalemic mixture of such supramolecular assemblies.</jats:p>

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