Copper‐Catalyzed <i>sp</i><sup><i>3</i></sup>‐Carbon Radical/Halogen Radical Cross Coupling: Selective Halogenation of 1,3‐Dicarbonyl Compounds
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- Shuai‐Shuai Lv
- Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Material Sciences Soochow University Suzhou, Jiangsu 215123 China
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- Xu‐Ping Yan
- Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Material Sciences Soochow University Suzhou, Jiangsu 215123 China
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- Cheng‐Kun Li
- Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Material Sciences Soochow University Suzhou, Jiangsu 215123 China
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- Shao‐Fang Zhou
- Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Material Sciences Soochow University Suzhou, Jiangsu 215123 China
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- Adedamola Shoberu
- Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Material Sciences Soochow University Suzhou, Jiangsu 215123 China
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- Jian‐Ping Zou
- Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Material Sciences Soochow University Suzhou, Jiangsu 215123 China
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説明
<jats:title>Abstract</jats:title><jats:p>A new copper‐catalyzed sp<jats:sup>3</jats:sup>‐carbon radical/halogen radical cross‐coupling strategy for the formation of C(sp<jats:sup>3</jats:sup>)‐X bond is described. This provides a general method for synthesis of <jats:italic>α</jats:italic>‐halogenated and <jats:italic>α</jats:italic>,<jats:italic>α</jats:italic>‐dihalogenated‐1,3‐dicarbonyl compounds using sodium halides as halogen source under mild conditions.</jats:p>
収録刊行物
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- ChemistrySelect
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ChemistrySelect 5 (19), 5670-5674, 2020-05-18
Wiley