Photodissociation Reaction from Higher Excited Triplet States of [2.2]Paracyclophane
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- Shun-ichi Ishikawa
- The Institute for Solid State Physics, The University of Tokyo
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- Junko Nakamura
- The Institute of Physical and Chemical Research
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- Saburo Nagakura
- The Institute for Solid State Physics, The University of Tokyo
書誌事項
- 公開日
- 1981-03-01
- 権利情報
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- https://academic.oup.com/pages/standard-publication-reuse-rights
- DOI
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- 10.1246/bcsj.54.685
- 公開者
- Oxford University Press (OUP)
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説明
<jats:title>Abstract</jats:title> <jats:p>The mechanism of photodissociation of [2.2]paracyclophane in glassy solvent at 77 K was studied. It is concluded that the dissociation of the CH2–CH2 bridge occurs from higher triplet states (Tn) via the lowest triplet state as an intermediate. The efficiency of the reaction depends on the characters of Tn states; high from the locally excited state, and low from the charge-transfer state.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 54 (3), 685-686, 1981-03-01
Oxford University Press (OUP)
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キーワード
詳細情報 詳細情報について
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- CRID
- 1360565169055100928
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- NII論文ID
- 130001987191
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- ISSN
- 13480634
- 00092673
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