A Dinuclear Zinc Complex, [Zn2(μ-H2THBQ)(TPA)2](ClO4)2, [TPA = Tris(2-pyridylmethyl)amine; H2THBQ2− = 2,3,5,6-Tetrahydroxy-1,4-benzoquinonate], Exhibiting Two-proton Coupled Two-electron Donating Ability
-
- Eiji Asato
- Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus
-
- Shoji Miyazato
- Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus
-
- Haruka Tohma
- Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus
-
- Satoshi Takara
- Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus
-
- Makoto Tadokoro
- Department of Chemistry, Faculty of Science, Tokyo University of Science
-
- Yuji Miyazato
- Department of Chemistry, Faculty of Science, Tokyo University of Science
-
- Daisuke Yoshioka
- School of Science and Technology, Kwansei Gakuin University
-
- Masahiro Mikuriya
- School of Science and Technology, Kwansei Gakuin University
Search this article
Description
<jats:title>Abstract</jats:title> <jats:p>The reaction of Zn(ClO4)2·6H2O with TPA and H4THBQ in methanol gave air-sensitive crystalline powder [Zn2(μ-H2THBQ)(TPA)2](ClO4)2 (1). An equimolar reaction of 1 with 1,4-benzoquinone (BQ) in acetonitrile under Ar atmosphere quantitatively produced 1,4-hydroquinone and [Zn2(μ-RHOD)(TPA)2](ClO4)2 (2) as a result of the 2H+, 2e proton-coupled electron-transfer (PCET) reaction.</jats:p>
Journal
-
- Chemistry Letters
-
Chemistry Letters 38 (12), 1170-1171, 2009-11-07
Oxford University Press (OUP)
Related Data
See more- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1360565169064654336
-
- NII Article ID
- 10027175799
-
- NII Book ID
- AA00603318
-
- ISSN
- 13480715
- 03667022
-
- Data Source
-
- Crossref
- CiNii Articles
- OpenAIRE