A Dinuclear Zinc Complex, [Zn2(μ-H2THBQ)(TPA)2](ClO4)2, [TPA = Tris(2-pyridylmethyl)amine; H2THBQ2− = 2,3,5,6-Tetrahydroxy-1,4-benzoquinonate], Exhibiting Two-proton Coupled Two-electron Donating Ability

DOI PDF 研究データあり 被引用文献1件 参考文献18件
  • Eiji Asato
    Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus
  • Shoji Miyazato
    Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus
  • Haruka Tohma
    Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus
  • Satoshi Takara
    Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus
  • Makoto Tadokoro
    Department of Chemistry, Faculty of Science, Tokyo University of Science
  • Yuji Miyazato
    Department of Chemistry, Faculty of Science, Tokyo University of Science
  • Daisuke Yoshioka
    School of Science and Technology, Kwansei Gakuin University
  • Masahiro Mikuriya
    School of Science and Technology, Kwansei Gakuin University

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<jats:title>Abstract</jats:title> <jats:p>The reaction of Zn(ClO4)2·6H2O with TPA and H4THBQ in methanol gave air-sensitive crystalline powder [Zn2(μ-H2THBQ)(TPA)2](ClO4)2 (1). An equimolar reaction of 1 with 1,4-benzoquinone (BQ) in acetonitrile under Ar atmosphere quantitatively produced 1,4-hydroquinone and [Zn2(μ-RHOD)(TPA)2](ClO4)2 (2) as a result of the 2H+, 2e proton-coupled electron-transfer (PCET) reaction.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 38 (12), 1170-1171, 2009-11-07

    Oxford University Press (OUP)

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