An <i>N</i>-Heterocyclic Carbene−Disilyne Complex and Its Reactivity toward ZnCl<sub>2</sub>
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- Torahiko Yamaguchi
- Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan, and Institute of Chemistry, Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17 Juni 135, Sekr. C2, D-10623 Berlin, Germany
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- Akira Sekiguchi
- Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan, and Institute of Chemistry, Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17 Juni 135, Sekr. C2, D-10623 Berlin, Germany
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- Matthias Driess
- Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan, and Institute of Chemistry, Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17 Juni 135, Sekr. C2, D-10623 Berlin, Germany
書誌事項
- 公開日
- 2010-09-15
- 資源種別
- journal article
- DOI
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- 10.1021/ja107160g
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
The reaction of disilyne 1 with 1,3,4,5-tetramethylimidazol-2-ylidene (an N-heterocyclic carbene, NHC) produced the disilyne-NHC complex 2, RLSi═SiR: (R = Si(i)Pr[CH(SiMe(3))(2)](2), L = NHC), with a trans geometry of the Si═Si moiety and lone-pair electrons residing on one of the double-bonded Si atoms. Upon complexation of 2 with ZnCl(2), the disilyne-NHC-ZnCl(2) complex 3 was produced, in which the Si═Si bond adopted the cis geometry.
収録刊行物
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- Journal of the American Chemical Society
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Journal of the American Chemical Society 132 (40), 14061-14063, 2010-09-15
American Chemical Society (ACS)
