Mechanistic insights into intramolecular ortho-amination/hydroxylation by nonheme Fe<sup>IV</sup>NTs/Fe<sup>IV</sup>O species: the σ vs. the π channels
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- Bhawana Pandey
- Department of Chemistry
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- Madhavan Jaccob
- Department of Chemistry
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- Gopalan Rajaraman
- Department of Chemistry
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説明
<p>Intra molecular aromatic amination/hydroxylation by iron(<sc>iv</sc>)-species (imido and oxo). The following aspects are discussed in this study: (a) reasons for high reactivity; (b) comparative oxidative abilities; (c) prediction of σ and π pathways.</p>
収録刊行物
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- Chemical Communications
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Chemical Communications 53 (22), 3193-3196, 2017
Royal Society of Chemistry (RSC)