Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics
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- Michael S. Inkpen
- Department of Chemistry
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- Andrew J. P. White
- Department of Chemistry
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- Tim Albrecht
- Department of Chemistry
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- Nicholas J. Long
- Department of Chemistry
説明
<p>A much improved route to 1,1′-bis(arylethynyl)ferrocenes comprising <italic>accessible</italic> thiolates on the aryl ring is reported. Unanticipated reactions between AcCl, TBAF–BBr3 and ferrocenyl-alkynes are also discussed, offering a rationale for previous synthetic difficulties.</p>
収録刊行物
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- Dalton Trans.
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Dalton Trans. 43 (41), 15287-15290, 2014
Royal Society of Chemistry (RSC)
