Synthesis of 1‐Adamantylaminogermylene and Its Chalcogenation Reactions

DOI Web Site 研究データあり 参考文献90件
  • Mariko Yukimoto
    Institute for Chemical Research Kyoto University Gokasho 611-0011 Uji Kyoto Japan
  • Kazuaki Kanda
    Institute for Chemical Research Kyoto University Gokasho 611-0011 Uji Kyoto Japan
  • Takamasa Aoki
    Institute for Chemical Research Kyoto University Gokasho 611-0011 Uji Kyoto Japan
  • Yoshiyuki Mizuhata
    Institute for Chemical Research Kyoto University Gokasho 611-0011 Uji Kyoto Japan
  • Norihiro Tokitoh
    Institute for Chemical Research Kyoto University Gokasho 611-0011 Uji Kyoto Japan

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公開日
2024-01-12
資源種別
journal article
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/ejic.202300663
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>The synthesis, isolation, and characterization of 1‐adamantylaminogermylene <jats:bold>1</jats:bold> have been achieved utilizing kinetic stabilization with a bulky aryl group on the germanium atom. Aminogermylene <jats:bold>1</jats:bold> was found to be stable in toluene solution at 110 °C for 3 days without decomposition. The chalcogenation reaction of <jats:bold>1</jats:bold> aiming to synthesize heavy amides gave the head‐to‐tail type dimers of the corresponding heavy amides.</jats:p>

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