Photon-, Reductant-, and Oxidant-Induced Substitution of a CO Ligand on closo-[Cp*2Fe3S2(CO)3] (Cp* = η5-C5Me5)
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- Masahiro Yuki
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Toshiaki Mitsui
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Shinji Inomata
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Masaaki Okazaki
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Hiroshi Ogino
- Department of Chemistry, Graduate School of Science, Tohoku University
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<jats:title>Abstract</jats:title> <jats:p>Substitution of CO in closo-[Cp*2Fe3S2(CO)3] (1) by PPh3 was accelerated upon photolysis or by treatment with reductant or oxidant to give mono(PPh3)-substituted clusters. In the redoxinduced reaction, [1]− and [1]+ were proposed as labile intermediates to substitution of CO.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 27 (6), 561-562, 1998-06-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360846644039656576
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- NII論文ID
- 10004281333
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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