Mechanistic study on the reaction of pinB-BMes<sub>2</sub>with alkynes based on experimental investigation and DFT calculations: gradual change of mechanism depending on the substituent
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- Linlin Wu
- Department of Chemistry
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- Chiemi Kojima
- Department of Applied Chemistry
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- Ka-Ho Lee
- Department of Chemistry
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- Shogo Morisako
- Department of Molecular and Macromolecular Chemistry
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- Zhenyang Lin
- Department of Chemistry
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- Makoto Yamashita
- Department of Molecular and Macromolecular Chemistry
Description
<p>Combination of kinetic and DFT studies revealed a subtle balance for substituent effect toward the regioselectivity of the product in metal-free and base-catalyzed diboration of arylacetylenes.</p>
Journal
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- Chemical Science
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Chemical Science 12 (28), 9806-9815, 2021
Royal Society of Chemistry (RSC)
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Keywords
Details 詳細情報について
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- CRID
- 1360857593798651392
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- ISSN
- 20416539
- 20416520
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- Article Type
- journal article
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- Data Source
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- Crossref
- KAKEN
- OpenAIRE
