RAFT aqueous emulsion polymerization of methyl methacrylate: observation of unexpected constraints when employing a non-ionic steric stabilizer block
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- Derek H. H. Chan
- Dainton Building, Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK
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- Amy A. Cockram
- Dainton Building, Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK
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- Rebecca R. Gibson
- Dainton Building, Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK
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- Emily L. Kynaston
- Syngenta, Jealott's Hill International Research Centre, Bracknell, Berkshire, RG42 6EY, UK
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- Christopher Lindsay
- Syngenta, Jealott's Hill International Research Centre, Bracknell, Berkshire, RG42 6EY, UK
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- Philip Taylor
- Syngenta, Jealott's Hill International Research Centre, Bracknell, Berkshire, RG42 6EY, UK
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- Steven P. Armes
- Dainton Building, Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK
抄録
<jats:p>Using a <jats:italic>non-ionic</jats:italic> steric stabilizer for the RAFT aqueous emulsion polymerization of methyl methacrylate leads to flocculated nanoparticles when targeting DPs > 100; there is no such constraint when employing an <jats:italic>anionic</jats:italic> stabilizer block.</jats:p>
収録刊行物
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- Polymer Chemistry
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Polymer Chemistry 12 (40), 5760-5769, 2021
Royal Society of Chemistry (RSC)