Photomechanical Azobenzene Crystals

  • Takuya Taniguchi
    Center for Data Science, Waseda University, 27 Waseda-cho, Shinjuku-ku, Tokyo 1620042, Japan
  • Toru Asahi
    Department of Advanced Science and Engineering, Graduate School of Advanced Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 1698555, Japan
  • Hideko Koshima
    Research Organization for Nano & Life Innovation, Waseda University, 513 Wasedatsurumaki-cho, Shinjuku-ku, Tokyo 1620041, Japan

書誌事項

公開日
2019-08-22
資源種別
journal article
権利情報
  • https://creativecommons.org/licenses/by/4.0/
DOI
  • 10.3390/cryst9090437
公開者
MDPI AG

説明

<jats:p>Photomechanically responsive materials are promising candidates for future smart actuator applications. The photo-responsive behaviors originate from the photoisomerization of photochromic molecules. A typical photochromic compound, azobenzene, has been studied extensively in the solution state and has played a crucial role in the photomechanical behaviors of materials such as polymers and gels, via chemical bridging with their matrix. In contrast to polymers and gels, the photomechanical attributes of molecular crystals have not progressed to the same degree, due to their rigidity and fragility. However, the past decade has witnessed an increasing number of reports of the photomechanical motion of molecular crystals, including azobenzene crystals. This paper reviews the current state-of-the-art of mechanically responsive azobenzene crystals, including the history, crystal design strategy, and future promising applications.</jats:p>

収録刊行物

  • Crystals

    Crystals 9 (9), 437-, 2019-08-22

    MDPI AG

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