Cycloparaphenylene‐Based Ionic Donor–Acceptor Supramolecule: Isolation and Characterization of Li<sup>+</sup>@C<sub>60</sub>⊂[10]CPP
書誌事項
- 公開日
- 2015-02-18
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/ange.201500544
- 10.1002/anie.201500544
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>The first cycloparaphenylene (CPP)‐based ionic donor–acceptor supramolecule Li<jats:sup>+</jats:sup>@C<jats:sub>60</jats:sub>⊂[10]CPP⋅X<jats:sup>−</jats:sup> has been synthesized. X‐ray crystallography not only confirmed the molecular structure of Li<jats:sup>+</jats:sup>@C<jats:sub>60</jats:sub>⊂[10]CPP⋅X<jats:sup>−</jats:sup> but also uncovered the formation of a unique ionic crystal. The strong charge‐transfer interaction between [10]CPP and Li<jats:sup>+</jats:sup>@C<jats:sub>60</jats:sub>, which was confirmed by electrochemical measurement and spectroscopic analyses, caused significant delocalization of the positive charge across the entire complex.</jats:p>
収録刊行物
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- Angewandte Chemie
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Angewandte Chemie 127 (12), 3778-3782, 2015-02-18
Wiley