Silver‐Mediated Oxidative Aliphatic CH Trifluoromethylthiolation

Shuo Guo, Xiaofei Zhang, Pingping Tang

doi:10.1002/ange.201411807

Silver‐Mediated Oxidative Aliphatic CH Trifluoromethylthiolation

DOI Web Site Web Site 被引用文献1件

書誌事項

公開日: 2015-02-25

権利情報

http://onlinelibrary.wiley.com/termsAndConditions#vor

DOI

10.1002/ange.201411807

公開者: Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>The first example of a practical and direct trifluoromethylthiolation reaction of unactivated aliphatic CH bonds employs a silver‐based reagent. The reaction is operationally simple, scalable, and proceeds under aqueous conditions in air. Furthermore, its broad scope and good functional‐group compatibility were demonstrated by applying this method to the selective trifluoromethylthiolation of natural products and natural‐product derivatives.</jats:p>