Sulfoximines as a Versatile Scaffold for Electrophilic Fluoroalkylating Reagents

Céline Urban, Frédéric Cadoret, Jean‐Claude Blazejewski, Emmanuel Magnier

doi:10.1002/ejoc.201100503

Sulfoximines as a Versatile Scaffold for Electrophilic Fluoroalkylating Reagents

DOI Web Site Web Site 被引用文献8件

書誌事項

公開日: 2011-07-11

権利情報

http://onlinelibrary.wiley.com/termsAndConditions#vor

DOI

10.1002/ejoc.201100503

公開者: Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>New electrophilic fluoroalkylating agents based on the sulfoximine skeleton as a common platform are described. We demonstrate the importance of the activating group, attached to the nitrogen, and its specificity for the fluorinated group to be delivered. As an application, a variety of unknown dichlorofluoro, bromodifluoro, and trifluoromethyl alkynes have been prepared using these reagents.</jats:p>