Competition between energy and phase relaxation in electronic curve crossing processes

DOI PDF 被引用文献6件
  • John M. Jean
    Department of Chemistry, Washington University, St. Louis, Missouri 63130
  • Graham R. Fleming
    Department of Chemistry and The James Franck Institute, University of Chicago, Chicago, Illinois 60637

書誌事項

公開日
1995-08-08
DOI
  • 10.1063/1.469684
公開者
AIP Publishing

この論文をさがす

説明

<jats:p>We present results from simulations of vibrational energy and phase relaxation and electronic curve crossing using a multilevel formulation of Redfield theory, which demonstrate the shortcomings of the optical Bloch approximation and the importance of coherence transfer processes in the relaxation dynamics of multilevel systems. Specifically, we show that for a harmonic well, energy relaxation can occur with retention of vibrational phase, and that for sufficiently strong electronic coupling, the product of an electronic curve crossing process can be formed vibrationally coherent even when no coherence is present in the initially excited state.</jats:p>

収録刊行物

被引用文献 (6)*注記

もっと見る

詳細情報 詳細情報について

問題の指摘

ページトップへ