Fluorinated Johnson Reagent for Transfer‐Trifluoromethylation to Carbon Nucleophiles

DOI DOI Web Site Web Site 研究データあり 被引用文献14件

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公開日
2008-06-23
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/ejoc.200800419
  • 10.1002/chin.200842035
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>A novel reagent, [(oxido)phenyl(trifluoromethyl)‐λ<jats:sup>4</jats:sup>‐sulfanylidene]dimethylammonium tetrafluoroborate has been developed for the electrophilic trifluoromethylation of carbon nucleophiles. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent. The firstexample of vinylogous trifluoromethylation of dicyanoalkylidenes is also demonstrated.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p>

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