Solvent-Induced Controllable Synthesis, Single-Crystal to Single-Crystal Transformation and Encapsulation of Alq3 for Modulated Luminescence in (4,8)-Connected Metal–Organic Frameworks
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- Ya-Qian Lan
- National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan
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- Hai-Long Jiang
- National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan
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- Shun-Li Li
- Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China
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- Qiang Xu
- National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan
書誌事項
- 公開日
- 2012-06-26
- DOI
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- 10.1021/ic202635a
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
In this work, for the first time, we have systematically demonstrated that solvent plays crucial roles in both controllable synthesis of metal-organic frameworks (MOFs) and their structural transformation process. With solvent as the only variable, five new MOFs with different structures have been constructed, in which one MOF undergoes solvent-induced single-crystal to single-crystal (SCSC) transformation that involves not only solvent exchange but also the cleavage and formation of coordination bonds. Particularly, a significant crystallographic change has been realized through an unprecedented three-step SCSC transformation process. Furthermore, we have demonstrated that the obtained MOF could be an excellent host for chromophores such as Alq3 for modulated luminescent properties.
収録刊行物
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- Inorganic Chemistry
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Inorganic Chemistry 51 (14), 7484-7491, 2012-06-26
American Chemical Society (ACS)
