Transformation of Coordinated Dinitrogen by Reaction with Dihydrogen and Primary Silanes
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- Michael D. Fryzuk
- M. D. Fryzuk, J. B. Love, S. J. Rettig, Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada.
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- Jason B. Love
- M. D. Fryzuk, J. B. Love, S. J. Rettig, Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada.
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- Steven J. Rettig
- M. D. Fryzuk, J. B. Love, S. J. Rettig, Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada.
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- Victor G. Young
- V. G. Young, Chemistry Department, University of Minnesota, Minneapolis, MN 55455, USA.
書誌事項
- 公開日
- 1997-03-07
- DOI
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- 10.1126/science.275.5305.1445
- 公開者
- American Association for the Advancement of Science (AAAS)
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説明
<jats:p>The reaction of dihydrogen with a side-on bound dinitrogen complex of zirconium was investigated. Instead of a displacement of the dinitrogen moiety, which is the common mode of reactivity, a complex containing both a bridging hydride and a bridging hydrazido unit with a nitrogen-hydrogen bond was observed. This reaction was extended to primary silanes to produce a species that contained a nitrogen-silicon bond. In addition, an intermediate in the dihydrogen addition has been structurally characterized as having a bridging dihydrogen unit.</jats:p>
収録刊行物
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- Science
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Science 275 (5305), 1445-1447, 1997-03-07
American Association for the Advancement of Science (AAAS)
