Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex
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- Jing‐Jing Guo
- School of Physical Science and Technology ShanghaiTech University Shanghai 201210 China
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- Anhua Hu
- School of Physical Science and Technology ShanghaiTech University Shanghai 201210 China
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- Yilin Chen
- School of Physical Science and Technology ShanghaiTech University Shanghai 201210 China
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- Jianfeng Sun
- School of Physical Science and Technology ShanghaiTech University Shanghai 201210 China
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- Haoming Tang
- School of Physical Science and Technology ShanghaiTech University Shanghai 201210 China
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- Zhiwei Zuo
- School of Physical Science and Technology ShanghaiTech University Shanghai 201210 China
書誌事項
- 公開日
- 2016-11-11
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/ange.201609035
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>A general strategy for the cleavage and amination of C−C bonds of cycloalkanols has been achieved through visible‐light‐induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C−C bond cleavage and functionalization of unstrained secondary cycloalkanols.</jats:p>
収録刊行物
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- Angewandte Chemie
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Angewandte Chemie 128 (49), 15545-15548, 2016-11-11
Wiley
