Copper‐Catalyzed Regioselective Oxytrifluoromethylation of Allenes Using a CF<sub>3</sub>‐Transfer Reagent

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Published
2014-09-10
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  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/adsc.201400320
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Wiley

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<jats:title>Abstract</jats:title><jats:p>A mild and efficient copper‐catalyzed oxytrifluoromethylation of allenes is demonstrated. The reaction tolerates a range of substrates to give a series of trifluoromethylated derivatives in moderate to good yields. Two possible pathways were proposed based on the reaction results and control experiments.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/gif" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mcontent.gif"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>

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