Metal‐Free Direct Aryltrifluoromethylation of Allylic Alcohols with Langlois’ Reagent through Concomitant 1,2‐Aryl Migration
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- Hong‐Li Huang
- State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology Harbin 150080 P. R. China
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- Hang Yan
- State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology Harbin 150080 P. R. China
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- Guo‐Lin Gao
- State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology Harbin 150080 P. R. China
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- Chao Yang
- State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology Harbin 150080 P. R. China
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- Wujiong Xia
- State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology Harbin 150080 P. R. China
書誌事項
- 公開日
- 2015-04-27
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/ajoc.201500096
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>A metal‐free and cost‐effective synthetic protocol for selective aryltrifluoromethylation of allylic alcohols with Langlois’ reagent (CF<jats:sub>3</jats:sub>SO<jats:sub>2</jats:sub>Na) through cascade trifluoromethyl radical addition/1,2‐aryl migration has been developed. The highlights of this procedure are operational simplicity, excellent functional group tolerance, and mild reaction conditions.</jats:p>
収録刊行物
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- Asian Journal of Organic Chemistry
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Asian Journal of Organic Chemistry 4 (7), 674-677, 2015-04-27
Wiley