Rhodium‐Catalyzed NH Insertion of Pyridyl Carbenes Derived from Pyridotriazoles: A General and Efficient Approach to 2‐Picolylamines and Imidazo[1,5‐<i>a</i>]pyridines

Yi Shi, Anton V. Gulevich, Vladimir Gevorgyan

doi:10.1002/anie.201408335

Rhodium‐Catalyzed NH Insertion of Pyridyl Carbenes Derived from Pyridotriazoles: A General and Efficient Approach to 2‐Picolylamines and Imidazo[1,5‐<i>a</i>]pyridines

DOI Web Site Web Site 被引用文献1件

書誌事項

公開日: 2014-10-21

権利情報

http://onlinelibrary.wiley.com/termsAndConditions#vor

DOI

10.1002/anie.201408335

公開者: Wiley

この論文をさがす

CiNii Books

説明

<jats:title>Abstract</jats:title><jats:p>A general and efficient NH insertion reaction of rhodium pyridyl carbenes derived from pyridotriazoles was developed. Various NH‐containing compounds, including amides, anilines, enamines, and aliphatic amines, smoothly underwent the NH insertion reaction to afford 2‐picolylamine derivatives. The developed transformation was further utilized in a facile one‐pot synthesis of imidazo[1,5‐a]pyridines.</jats:p>