Experimental and Theoretical Studies of Homoleptic Tellurium Cyanides Te(CN)<sub><i>x</i></sub>: Crystal Structure of Te(CN)<sub>2</sub>
書誌事項
- 公開日
- 2004-12
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/ejic.200400763
- 公開者
- Wiley
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説明
<jats:title>Abstract</jats:title><jats:p>The labile tellurium cyanide species Te(CN)<jats:sub>2</jats:sub> and Te(CN)<jats:sub>4</jats:sub> have been prepared by treatment of tellurium(<jats:sc>IV</jats:sc>) tetrahalides with cyanide. Both are thermosensitive solids and, in addition, the tetracyanide was found to be pyrophoric. The crystal structure of Te(CN)<jats:sub>2</jats:sub> has been determined. The structures of Te(CN)<jats:sub>2</jats:sub>, Te(CN)<jats:sub>4</jats:sub>, and Te(CN)<jats:sub>6</jats:sub> have been calculated at various levels of theory. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)</jats:p>
収録刊行物
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- European Journal of Inorganic Chemistry
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European Journal of Inorganic Chemistry 2004 (24), 4764-4769, 2004-12
Wiley
