Electron‐Catalyzed Fluoroalkylation of Vinyl Azides

  • Emily G. Mackay
    Westfälische Wilhelms Universität Organisch-Chemisches Institut Corrensstrasse 40 48149 Münster Germany
  • Armido Studer
    Westfälische Wilhelms Universität Organisch-Chemisches Institut Corrensstrasse 40 48149 Münster Germany

書誌事項

公開日
2016-07-19
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/chem.201602855
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>The transition‐metal free fluoroalkylation of vinyl azides is herein reported. This operationally simple reaction employs the Togni reagent as a CF<jats:sub>3</jats:sub> source, Bu<jats:sub>4</jats:sub>NI as an initiator, and occurs under electron catalysis. A range of readily prepared starting materials are functionalized using this approach to produce both phenanthridines and quinoxalin‐2‐ones.</jats:p>

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