Acyl Radical Chemistry via Visible-Light Photoredox Catalysis

DOI PDF 被引用文献11件

書誌事項

公開日
2018-12-12
DOI
  • 10.1055/s-0037-1610329
公開者
Georg Thieme Verlag KG

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説明

<jats:p>Visible-light photoredox catalysis enables easy access to acyl radicals under mild reaction conditions. Reactive acyl radicals, generated from various acyl precursors such as aldehydes, α-keto acids, carboxylic acids, anhydrides, acyl thioesters, acyl chlorides, or acyl silanes, can undergo a diverse range of synthetically useful transformations, which were previously difficult or inaccessible. This review summarizes the recent progress on visible-light-driven acyl radical generation using transition-metal photoredox catalysts, metallaphotocatalysts, hypervalent iodine catalysts or organic photocatalysts.</jats:p><jats:p>1 Introduction</jats:p><jats:p>2 The Scope of This Review</jats:p><jats:p>3 Aldehydes as a Source of Acyl Radicals</jats:p><jats:p>4 α-Keto Acids as a Source of Acyl Radicals</jats:p><jats:p>5 Carboxylic Acids as a Source of Acyl Radicals</jats:p><jats:p>6 Anhydrides as a Source of Acyl Radicals</jats:p><jats:p>7 Acyl Thioesters as a Source of Acyl Radicals</jats:p><jats:p>8 Acyl Chlorides as a Source of Acyl Radicals</jats:p><jats:p>9 Acyl Silanes as a Source of Acyl Radicals</jats:p><jats:p>10 Conclusions and Future Outlook</jats:p>

収録刊行物

  • Synthesis

    Synthesis 51 (02), 303-333, 2018-12-12

    Georg Thieme Verlag KG

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