Nickel‐Catalyzed Synthesis of Phosphonium Salts from Aryl Halides and Triphenylphosphine

David Marcoux, André B. Charette

doi:10.1002/adsc.200800542

Nickel‐Catalyzed Synthesis of Phosphonium Salts from Aryl Halides and Triphenylphosphine

DOI Web Site Web Site 被引用文献7件

書誌事項

公開日: 2008-12

権利情報

http://onlinelibrary.wiley.com/termsAndConditions#vor

DOI

10.1002/adsc.200800542

公開者: Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>An efficient method to synthesize functionalized tetraarylphosphonium salts is described. The nickel‐catalyzed coupling reaction between aryl iodides, bromides, chlorides, or triflates and triphenylphosphine generates tetraarylphosphonium salts in high yields. The coupling is wide in scope and tolerates a variety of functional groups such as alcohols, amides, ketones, aldehydes, phenols, phosphines and amines.</jats:p>