One-Dimensionally Extended Paddlewheel Dirhodium Complexes from Metal–Metal Bonds with Diplatinum Complexes
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- Kazuhiro Uemura
- Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu, 501-1193, Japan
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- Masahiro Ebihara
- Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu, 501-1193, Japan
書誌事項
- 公開日
- 2011-07-26
- DOI
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- 10.1021/ic200786k
- 公開者
- American Chemical Society (ACS)
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説明
We have succeeded in obtaining unique one-dimensional (1D) chain complexes (1, 2, and 3) comprised of two types of metal species: rhodium and platinum. These compounds are constructed from a dinuclear rhodium complex (i.e., [Rh(2)]) and a pivalamidate-bridged platinum complex (i.e., [Pt(2)]), forming an attractive quasi-1D infinite chain, expressed as -{[Rh(2)]-[Pt(2)]-[Pt(2)]}(n)-. Interestingly, the bridging ligands of [Rh(2)] can be varied with trifluoroacetate, acetate, and acetamidate groups, indicating the possibility of electronic structure modulation in the 1D chain.
収録刊行物
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- Inorganic Chemistry
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Inorganic Chemistry 50 (17), 7919-7921, 2011-07-26
American Chemical Society (ACS)
