Synthesis, Structures, and Optical and Electrochemical Properties of Benzoporphycenes

Daiki Kuzuhara, John Mack, Hiroko Yamada, Tetsuo Okujima, Noboru Ono, Nagao Kobayashi

doi:10.1002/chem.200900755

Synthesis, Structures, and Optical and Electrochemical Properties of Benzoporphycenes

DOI Web Site Web Site PubMed 被引用文献23件

書誌事項

公開日: 2009-09-28

権利情報

http://onlinelibrary.wiley.com/termsAndConditions#vor

DOI

10.1002/chem.200900755

公開者: Wiley

この論文をさがす

CiNii Books

説明

<jats:title>Abstract</jats:title><jats:p>The first facile syntheses of free‐base di‐ and tetrabenzoporphycenes and their metal complexes are reported, based on retro‐Diels–Alder reactions of the corresponding bicyclo[2.2.2]octadiene‐fused porphycenes, prepared by McMurray coupling of α,α′‐diformyldipyrrole. The photophysical and electrochemical properties are analyzed based on UV/Vis absorption, magnetic circular dichroism (MCD), and fluorescence emission, lifetime and quantum yield measurements, cyclic and differential pulse voltammetry (CV and DPV) and time‐dependent DFT calculations based on B3LYP geometry optimizations. Benzoporphycenes are found to be prime candidates for future use in photodynamic therapy.</jats:p>