Electronic structures of highly deformed iron(III) porphyrin complexes

Mikio Nakamura

doi:10.1016/j.ccr.2006.03.001

Electronic structures of highly deformed iron(III) porphyrin complexes

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Mikio Nakamura

書誌事項

公開日: 2006-09

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DOI

10.1016/j.ccr.2006.03.001

公開者: Elsevier BV

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説明

Abstract This review describes the effects of highly deformed porphyrin ring on the electronic structures of iron(III) porphyrinates, which includes (i) the electron configurations in low-spin ( S = 1/2) ruffled complexes, (ii) the contribution of the intermediate-spin ( S = 3/2) state in the spin-admixed ( S = 5/2, 3/2) complexes with ruffled and saddled porphyrin ring, and (iii) the novel spin crossover ( S = 1/2, S = 3/2) phenomenon in saddled complexes, with a special emphasis on the use of 1 H NMR, 13 C NMR, and EPR spectroscopy.