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- Jingang Zhou
- The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan
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- Jim J. Lin
- The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan
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- Weicheng Shiu
- The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan
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- Shih-Chieh Pu
- The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan
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- Kopin Liu
- The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan
書誌事項
- 公開日
- 2003-08-01
- DOI
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- 10.1063/1.1587112
- 公開者
- AIP Publishing
この論文をさがす
説明
<jats:p>The title reaction was investigated in a crossed-beam experiment. A (2+1) resonance-enhanced multiphon ionization technique was used to interrogate the internal-state distributions of the CD3 product at three different collision energies. Only the ν2 (umbrella) mode excitation was observed. Its distribution changes from a monotonically declined distribution at low energy to a slightly inverted one at higher collision energy. Although the rotational excitations of CD3 were small, a strong preference for K=0 was found, indicative of the dominance of the tumbling rotation motion of the CD3 product. The vibration-resolved excitation functions were also measured for ν2=0–3. A reaction barrier of 0.5 kcal/mol was deduced.</jats:p>
収録刊行物
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- The Journal of Chemical Physics
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The Journal of Chemical Physics 119 (5), 2538-2544, 2003-08-01
AIP Publishing
