Silver‐Catalyzed Oxidative C(sp<sup>3</sup>)−P Bond Formation through C−C and P−H Bond Cleavage

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  • Lili Li
    School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
  • Wenbin Huang
    School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
  • Lijin Chen
    School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
  • Jiaxing Dong
    School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
  • Xuebing Ma
    School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
  • Yungui Peng
    School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China

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<jats:title>Abstract</jats:title><jats:p>The silver‐catalyzed oxidative C(sp<jats:sup>3</jats:sup>)−H/P−H cross‐coupling of 1,3‐dicarbonyl compounds with H‐phosphonates, followed by a chemo‐ and regioselective C(sp<jats:sup>3</jats:sup>)−C(CO) bond‐cleavage step, provided heavily functionalized β‐ketophosphonates. This novel method based on a readily available reaction system exhibits wide scope, high functional‐group tolerance, and exclusive selectivity.</jats:p>

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