Silver‐Catalyzed Oxidative C(sp<sup>3</sup>)−P Bond Formation through C−C and P−H Bond Cleavage
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- Lili Li
- School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
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- Wenbin Huang
- School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
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- Lijin Chen
- School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
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- Jiaxing Dong
- School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
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- Xuebing Ma
- School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
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- Yungui Peng
- School of Chemistry and Chemical Engineering Southwest University 2 Tiansheng Road, Beibei Chongqing 400715 P.R. China
説明
<jats:title>Abstract</jats:title><jats:p>The silver‐catalyzed oxidative C(sp<jats:sup>3</jats:sup>)−H/P−H cross‐coupling of 1,3‐dicarbonyl compounds with H‐phosphonates, followed by a chemo‐ and regioselective C(sp<jats:sup>3</jats:sup>)−C(CO) bond‐cleavage step, provided heavily functionalized β‐ketophosphonates. This novel method based on a readily available reaction system exhibits wide scope, high functional‐group tolerance, and exclusive selectivity.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 56 (35), 10539-10544, 2017-07-21
Wiley
