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Nickel(0)-Catalyzed Dimerization of Ethyl Cyclopropylideneacetates
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- Taishi Kawasaki
- Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan, and Institute for Chemical Reaction Science, Tohoku University, Sendai 980-8578, Japan
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- Shinichi Saito
- Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan, and Institute for Chemical Reaction Science, Tohoku University, Sendai 980-8578, Japan
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- Yoshinori Yamamoto
- Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan, and Institute for Chemical Reaction Science, Tohoku University, Sendai 980-8578, Japan
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Description
The dimerization of ethyl cyclopropylideneacetates proceeded in the presence of Ni(0) catalysts, and cyclic compounds or linear compounds were formed in selective manners. The structures of products were highly dependent on the structure of the substrate and the ligands bound to the catalyst. The mechanism of the reactions was discussed in detail.
Journal
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- The Journal of Organic Chemistry
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The Journal of Organic Chemistry 67 (14), 4911-4915, 2002-06-06
American Chemical Society (ACS)
