Enzymatic Synthesis of Capric Acid-Rich Structured Lipids (MUM type) Using Candida antarctica Lipase
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- SilRoy Sumita
- Department of Chemical Technology, University College of Science & Technology, University of Calcutta
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- Ghosh Mahua
- Department of Chemical Technology, University College of Science & Technology, University of Calcutta
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The objective of the work was to produce capric acid rich structured lipids starting from various Indian indigenous vegetable oils, such as rice bran, ground nut and mustard oils. Acidolysis reaction between individual vegetable oils and capric acid in one is to three molar ratios at 45 degree centigrade temperature was carried out using position specific Candida antarctica lipase so as to protect the Sn-2 position of the oils which are rich in unsaturated fatty acids. The incorporation of capric acid depended on the reaction time showing 6 % within 6 h and 30.8 % in 72 h with rice bran oil. Similarly, in ground nut oil incorporation of capric acid was 34.2 % in 72 h compared to 5.3 % in 6 h. Thus mustard oil showed much lower incorporation than the other two oils, with 3.3 % and 19.5 % in 6 and 72 h respectively. The incorporation of capric acid was influenced by the nature of the fatty acids present in the original oil. The fatty acid composition of Sn-2 position of the structured triacylglycerols of the three oils revealed that capric acid was mainly replacing the fatty acids occupying the Sn-1 and 3 positions of the triglyceride molecule.
収録刊行物
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- Journal of Oleo Science
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Journal of Oleo Science 60 (6), 275-280, 2011
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204091430528
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- NII論文ID
- 130000833476
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- NII書誌ID
- AA11503337
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- ISSN
- 13473352
- 13458957
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- NDL書誌ID
- 11078583
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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