添加剤フリーワット浴から得られたニッケルめっきの硬度と組織に及ぼすパルス電解の影響

書誌事項

タイトル別名
  • Effect of Pulse Electrolysis on the Hardness and Texture of Nickel Deposit Obtained from Additive Free Watt Bath

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説明

Pulse plating was used to prepare nickel films from a Watts bath with no additives. The influences of the current pulse electrolysis parameters of duty ratio=0.03-0.33, Ton=0.1-5 ms, and Iav=2-10Adm-2, on the hardness, texture, and crystal orientation were investigated. Those characteristics were studied respectively using a nano-indenter hardness tester, scanning electron microscopy, and XRD. Results showed the importance of Iav for obtaining high-hardness films. The highest value of hardness was 4.5 GPa at Ton=1 ms, duty ratio=0.1, and Iav=10 Adm-2. Hardness is related closely to the texture. A Hall-Petch relation was observed between the hardness and grain size. The preferred orientation changed to the(311)→(220)→(200)plane with increase of the duty ratio when the pulse parameters were Ton=1 ms and Iav=5Adm-2.

収録刊行物

  • 表面技術

    表面技術 63 (9), 591-, 2012

    一般社団法人 表面技術協会

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詳細情報 詳細情報について

  • CRID
    1390001204117278720
  • NII論文ID
    10031075348
  • NII書誌ID
    AN1005202X
  • DOI
    10.4139/sfj.63.591
  • COI
    1:CAS:528:DC%2BC3sXos1Sr
  • ISSN
    18843409
    09151869
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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