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Polycyclic N-Heterocyclic Compounds. Part 59: Rearrangement Reactions of Fused Tricyclic 3-(2-Bromoethyl)pyrimidin-4(3H)-ones with Primary Amines via a Dimroth-Type Rearrangement
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- Okuda Kensuke
- Gifu Pharmaceutical University
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- Ohtomo Hiromi
- Faculty of Pharmaceutical Sciences, Okayama University
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- Tanaka Fumiaki
- Faculty of Pharmaceutical Sciences, Okayama University
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- Hirota Takashi
- Faculty of Pharmaceutical Sciences, Okayama University
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- Sasaki Kenji
- Faculty of Pharmaceutical Sciences, Okayama University
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Description
Reaction of some fused tricyclic 3-(2-bromoethyl)pyrimidin-4(3H)-ones with primary alkyl amines gave abnormal fused 3-alkyl-4-alkyliminopyrimidines via a Dimroth-type rearrangement, as well as normal substituted 3-(2-alkylaminoethyl) derivatives in methanol. This abnormal rearrangement reaction depended on reaction solvent.
Journal
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- Chemical and Pharmaceutical Bulletin
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Chemical and Pharmaceutical Bulletin 57 (7), 755-758, 2009
The Pharmaceutical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001204170320512
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- NII Article ID
- 130000124383
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- NII Book ID
- AA00602100
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- ISSN
- 13475223
- 00092363
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- NDL BIB ID
- 10264843
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- PubMed
- 19571428
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL Search
- Crossref
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed