Uniaxial Compression of the Halogen-Bridged Binuclear Metal Complex Pt<sub>2</sub>(<i>n</i>-butylCS<sub>2</sub>)<sub>4</sub>I

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  • Uniaxial Compression of the Halogen-Bridged Binuclear Metal Complex Pt2(n-butylCS2)4I

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Resistance measurements under uniaxial compression have been performed on the quasi-one-dimensional iodo-bridged diplatinum complex (MMX-chains) Pt2(n-butylCS2)4I between 100–355 K. The first-order phase transition between the low-temperature alternate-charge-polarization (ACP) state and room-temperature average-valence (AV) state (210 K at ambient pressure) shifted to a higher temperature under compression both parallel and perpendicular to the MMX chains. The stabilization of the ACP state by both compression directions indicates that the ligand molecules play a significant role in making the valence ordering state.

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