Uniaxial Compression of the Halogen-Bridged Binuclear Metal Complex Pt<sub>2</sub>(<i>n</i>-butylCS<sub>2</sub>)<sub>4</sub>I
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- Ito Hiroshi
- Department of Applied Physics, Nagoya University
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- Hasegawa Yasuhisa
- Department of Applied Physics, Nagoya University
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- Tanaka Hisaaki
- Department of Applied Physics, Nagoya University
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- Kuroda Shin-ichi
- Department of Applied Physics, Nagoya University
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- Mitsumi Minoru
- Department of Material Science, Himeji Institute of Technology
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- Toriumi Koshiro
- Department of Material Science, Himeji Institute of Technology
書誌事項
- タイトル別名
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- Uniaxial Compression of the Halogen-Bridged Binuclear Metal Complex Pt2(n-butylCS2)4I
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Resistance measurements under uniaxial compression have been performed on the quasi-one-dimensional iodo-bridged diplatinum complex (MMX-chains) Pt2(n-butylCS2)4I between 100–355 K. The first-order phase transition between the low-temperature alternate-charge-polarization (ACP) state and room-temperature average-valence (AV) state (210 K at ambient pressure) shifted to a higher temperature under compression both parallel and perpendicular to the MMX chains. The stabilization of the ACP state by both compression directions indicates that the ligand molecules play a significant role in making the valence ordering state.
収録刊行物
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 72 (9), 2149-2152, 2003
一般社団法人 日本物理学会
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詳細情報 詳細情報について
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- CRID
- 1390001204187496832
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- NII論文ID
- 210000104408
- 110001974298
- 130004538496
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- NII書誌ID
- AA00704814
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- BIBCODE
- 2003JPSJ...72.2149I
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- ISSN
- 13474073
- 00319015
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- NDL書誌ID
- 6684829
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可