Hydrogen Ion-Selective Poly(vinyl chloride) Membrane Electrode Based on a Calix[4]arene.
-
- KURUOGLU Demet
- Department of Chemistry, Faculty of Science, Ankara University
-
- CANEL Esin
- Department of Chemistry, Faculty of Science, Ankara University
-
- MEMON Shahabuddin
- Department of Chemistry, Selçuk University
-
- YILMAZ Mustafa
- Department of Chemistry, Selçuk University
-
- KILIÇ Esma
- Department of Chemistry, Faculty of Science, Ankara University
この論文をさがす
抄録
A hydrogen ion-selective poly(vinyl chloride) membrane electrode was constructed using 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetracyanomethoxycalix[4]arene as a neutral carrier. The electrode showed an apparent Nernstian response in the 2 - 11.5 pH range with a slope of 54.0±0.2 mV/pH at 20±1°C. This electrode showed a rapid response of the emf to changes in the pH, high ion selectivity with respect to lithium, sodium and potassium, and characteristics similar to those reported for the conventional pH glass membrane electrode. It can be used as a potentiometric indicator electrode in hydrofluoric acid solutions. The effects of iodide, thiocyanate, perchlorate and bromide on the characteristics of the electrode were also considered.
収録刊行物
-
- Analytical Sciences
-
Analytical Sciences 19 (2), 217-221, 2003
社団法人 日本分析化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390001204256633472
-
- NII論文ID
- 130004440699
- 80015808529
-
- NII書誌ID
- AA10500785
-
- COI
- 1:CAS:528:DC%2BD3sXhtlOgtrc%3D
-
- ISSN
- 13482246
- 09106340
-
- NDL書誌ID
- 6442846
-
- PubMed
- 12608748
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可
