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- FURUKAWA Isao
- Department of Applied Chemistry, Doshisha University
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- NISHIOKA Yoshihiro
- Department of Applied Chemistry, Doshisha University
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- HASHIMOTO Shizunobu
- Department of Applied Chemistry, Doshisha University
Bibliographic Information
- Other Title
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- トリフェニルホスフィン/四塩化炭素を用いるニトロアルカンからニトリルの合成
Abstract
The direct synthesis of nitriles [1] J has been carried out by the reaction of nitroalkanes with triphenylphosphine/carbon tetrachloride in the presence of triethylamine. The yields of [1] were 60-98%, and the presence of ethyl acrylate in this system gave a mixture of [1]and 2-isooxazoline derivatives [3]. On the basis of these results, it is concluded that the reaction proceeds through nitrile oxide [2], which is formed as an intermediate by the elimination of water from nitroalkane with triphenylphosphin/icarbon tetrachloride and then gives [1] by the deoxidation with excess triphenylphosphine.
Journal
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- NIPPON KAGAKU KAISHI
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NIPPON KAGAKU KAISHI 1983 (7), 1096-1098, 1983-07-10
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001204390619648
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- NII Article ID
- 130004157609
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- ISSN
- 21850925
- 03694577
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed