書誌事項
- タイトル別名
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- Synthesis of Nitrites from Nitroalkanes Using Triphenylphosphine/Carbon Tetrachloride
抄録
The direct synthesis of nitriles [1] J has been carried out by the reaction of nitroalkanes with triphenylphosphine/carbon tetrachloride in the presence of triethylamine. The yields of [1] were 60-98%, and the presence of ethyl acrylate in this system gave a mixture of [1]and 2-isooxazoline derivatives [3]. On the basis of these results, it is concluded that the reaction proceeds through nitrile oxide [2], which is formed as an intermediate by the elimination of water from nitroalkane with triphenylphosphin/icarbon tetrachloride and then gives [1] by the deoxidation with excess triphenylphosphine.
収録刊行物
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- 日本化学会誌(化学と工業化学)
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日本化学会誌(化学と工業化学) 1983 (7), 1096-1098, 1983-07-10
公益社団法人 日本化学会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390001204390619648
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- NII論文ID
- 130004157609
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- ISSN
- 21850925
- 03694577
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可