New Near-Infrared Spectrophotometry for d8 Metal Ions, NiII and PtII, with 2,2′-Dithiobis(1-aminonaphthalene) in Aqueous Micellar Solutions

  • Terazono Yukiko
    Department of Applied Chemistry, Graduate School of Engineering, Tohoku University
  • Hoshino Hitoshi
    Department of Applied Chemistry, Graduate School of Engineering, Tohoku University
  • Yotsuyanagi Takao
    Department of Applied Chemistry, Graduate School of Engineering, Tohoku University

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タイトル別名
  • New Near-Infrared Spectrophotometry for d<SUP>8</SUP> Metal Ions, Ni<SUP>II</SUP> and Pt<SUP>II</SUP>, with 2,2′-Dithiobis(1-aminonaphthalene) in Aqueous Micellar Solutions

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説明

1-Amino-2-naphthalenethiolate ion (C10H6NH2S), produced from 2,2′-dithiobis(1-aminonaphthalene) (DTAN), forms 1:2 chelates with d8 metal ions (NiII and PtII) in aqueous PONPE 20 micellar solutions, and then subsequent oxidation of the chelates with O2 yield new NIR-absorbing chelates [MII(C10H6NHS·)2]0. The remarkable NIR absorption properties are as follows: for PtII (794 nm) ε = 5.03 × 104 M cm−1; for NiII (884 nm) ε = 4.73 × 104 M−1 cm−1.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 28 (11), 1251-1252, 1999

    公益社団法人 日本化学会

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