飽和脂肪酸および芳香族酸のパラオキシフェナシルエステル

小菅 貞良, 古田 正次, 山口 起立

doi:10.2116/bunsekikagaku.17.310

飽和脂肪酸および芳香族酸のパラオキシフェナシルエステル

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小菅貞良

岐阜大学農学部農芸化学科
古田正次

岐阜大学農学部農芸化学科
山口起立

岐阜大学農学部農芸化学科

書誌事項

タイトル別名

<I>p</I>-Hydroxyphenacyl esters of saturated fatty acids and aromatic acids
ホウワシボウサンオヨビホウコウゾクサンノパラオキシフェナシルエステル
Analytical studies on fatty acids. I
脂肪酸に関する分析化学的研究 (第1報)

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説明

p-Hydroxyphenacyl esters of fatty acids were prepared as derivatives for separation and identification of fatty acids. p-Hydroxyphenacyl bromide used for their preparation was synthesized according to King-Ostrum's method, which involves selective bromination of ketones with copper (II) bromide.<BR>The p-hydroxyphenacyl esters of C₂C₂₀ saturated fatty acids and aromatic acids were obtained as colorless needles using p-hydroxyphenacyl bromide. It was found that the p-hydroxyphenacyl bromide serves as a useful reagent for the identification of saturated fatty acids and some aromatic acids. Properties of p-hydroxyphenacyl esters have also been investigated.