Synthesis and Crystal Structure of a Mononuclear Copper(II) Complex of N,N'-Bis-2,3,4-trihydroxybenzylidene-1,2-phenylendiamine

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  • KOIKAWA Masayuki
    Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University
  • MATSUDA Yayoi
    Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University
  • TOKII Tadashi
    Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University

書誌事項

公開日
2008
DOI
  • 10.2116/analscix.24.x283
公開者
社団法人 日本分析化学会

説明

The mononuclear complex [CuII(H4bzphen)]·CH3OH, [H6bzphen = N,N′-bis-2,3,4-trihydroxybenzylidene-1,2-phenylendiamine] was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic system, space group P21/n and Z = 4 with cell parameters a = 14.601(14)Å, b = 8.574(3)Å, c = 15.953(9)Å, β = 109.49(8)°, V = 1882.8(21)Å3. H6bzphen acts as a tetradentate planar ligand, and the copper(II) has tetragonal planar geometry. The crystal packing is stabilized by inter-molecular π-π stacking interactions and hydrogen bonds.

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