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- 竹内 正之
- 九州大学大学院工学研究科物質創造工学専攻
書誌事項
- タイトル別名
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- Molecular Design of Artificial Saccharide Receptors.
- ボロンサン オ モチイタ ジンコウ トウシツ レセプター ノ セッケイ ト キ
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For the development of new receptor molecules that can precisely recognize sugar molecules, we synthesized a number of diboronic acids. Since one boronic acid can react with two OH groups (one diol group) to form a boronate ester, one diboronic acid can immobilize two diol units to form a sugarcontaining macrocycle. The selectivity can be tuned by the relative spatial position of the two boronic acids and the complexation event can be read out by circular dichroism, UV-Vis, and fluorescence spectroscopy. The nature presents a variety of saccharide structures to us which are already utilized as a “recognition tag” or a “supramolecular building-blocks” in the life processes. If we gain some efficient interfaces to control chemical and physical properties of saccharides, it will become possible to mimic this chemistry in artificial systems. As a research target to challenge this new concept, we can now raise three examples which are currently studied in our laboratory.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 56 (10), 831-840, 1998
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205276878720
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- NII論文ID
- 10009343775
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 4577829
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可